The effects of surface-modified graphene nanoplatelets on the sliding wear properties of basalt fibers-reinforced epoxy composites

Possessing unique designs and properties absent in conventional materials, nanocomposites have made a remarkable imprint in science and technology. This is particularly true regarding the polymer matrix composites when they are further reinforced with nanoparticles. In this study, the effects of different weight percentages (0, 0.1, 0.2, 0.3, 0.4, and 0.5) of surface-modified graphene nanoplatelets (GNPs) on the microhardness and wear properties of basalt fibers/epoxy composites were investigated. The GNPs were surface modified by silane, and the composites were made by the hand lay-up method. The wear tests were conducted under two different loads of 20 and 40 N. The best wear properties were achieved at 0.3 wt % GNPs as a result of the GNPs' self-lubrication property and the formation of a stable transfer/lubricating film at the pin and disk interface. Moreover, the friction coefficient was lower at the higher normal load of 40 N. The microscopic studies by FESEM and SEM showed that the presence of GNPs up to 0.3 wt % led to the stability of the transfer/lubricating film by enhancing the adhesion of the basalt fibers to the epoxy resin. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47986.     

玄武岩纤维填料应用于两种混合生长反应器的评价

采用单丝直径微米级的伞状玄武岩纤维(BF)作为填料,将其引入序批式反应器(SBR)和后置缺氧反硝化SBR外聚合物(EPS)含量和扫描电子显微镜形貌图,考察了两种SHBR的污水处理效果。试验结果表明:基于SBR的SHBR的出水COD、氨氮、总氮去除率分别为83.2%、89.9%、86.8%;基于后置缺氧反硝化SBR的SHBR优良,而基于后置缺氧反硝化SBR的SHBR的脱氮效果得到进一步的优化和提升。两种SHBR的BF填料中EPS含量分析结果显示:在好氧环境下,蛋白质(PN)的含量高于多糖(PS)的含量;在缺氧条件下,PS的含量明显高于PN的含量。     

枣35断块沙三段玄武岩储层特征及成藏条件分析

从地质、地震、测井及试油试采等方面入手，并采用新技术，对自来屯构造枣35断块沙三段玄武岩储层特征及成藏条件进行了分析。其结果为该区下一步勘探、开发及进一步研究奠定了基础。     

玄武岩铸石技术在高炉冲渣沟中的应用

为解决5^#、6^#高炉冲渣沟原16Mn衬板因冲蚀、腐蚀磨损严重，局部翘曲变形的问题，采用耐蚀性及耐磨性均较好的玄武岩铸石板作为冲渣沟内衬。设计铸石板结构为防滑形并预留孔用螺栓锚固，增加了铸石板与底部灌浆料粘接的可靠性，采用CGM自流型灌浆料施工，工期仅为4天。应用3年后检查，铸石板仅有微量磨损．     

纤维对水泥土加固效果影响的试验研究

将短切玄武岩纤维和水泥掺入取自长春地区的黄土中,进行无侧限抗压强度试验。主要研究纤维掺量、纤维长度对纤维水泥土无侧限抗压强度特性的影响。试验结果表明：同一纤维质量掺入比下,随着纤维长度的增加,纤维水泥土抗压强度大体呈上凸型曲线形式,曲线最终趋于无纤维掺入的水泥土强度,说明纤维分布均匀性和纤维分布密度对强度影响较大;同一纤维长度下,纤维水泥土强度随纤维质量掺入比的增大呈波浪型曲线形式发展,第1次波峰值大于第2次波峰值,曲线最终趋于某个固定值,在实际工程应用中,可采用初次波峰的掺入量进行水泥土加固,达到预期加固效果的同时,能够大幅降低工程造价;同时,要充分考虑搅拌不均匀性对水泥土强度带来的影响,且不宜采用过长的纤维进行加固,一方面容易形成集束现象,另一方面容易连挂在搅拌器械上。     

玄武岩连续纤维及其复合材料

介绍了玄武岩连续纤维及其复合材料在国内外发展的历史和现状,以及该新材料的主要特点、应用领域。     

玄武岩连续纤维的制备

利用坩埚法制备玄武岩连续纤维。研究了玄武岩纤维的熔融过程和拉丝工艺以及玄武岩纤维的基本特性。结果表明:选择陕西略阳辉绿岩矿作为玄武岩连续纤维的原矿,采用分体式氧化铝氧化铬坩埚,高度为13 mm,孔径为4 mm,台阶式漏嘴纺制玄武岩连续纤维,最长能成形15 m,纤维直径为12．2μm。     

Mechanical Properties of Phenolic-Resin Composites Reinforced with CF/BF Interlayer Hybrid Fibers

Phenolic-resin composites reinforced with carbon fiber (CF) and basalt fiber (BF) interlayer hybrid fibers plain fabric were fabricated. The tensile strength, compressive strength and interlaminar shear strength of the prepared composites were studied. The results indicated that hybrid fibers reinforced composites possessed the advantages of both CF and BF. When resin content was 35% by volume fraction, the comprehensive mechanical performance of BF/CF reinforced phenolic resin composites reached the optimal values with the warp and weft direction tensile strength, compressive strength and interlayer shear strength being 252 MPa and 487 MPa, 105 MPa and 129 MPa, 21 MPa and 20 MPa, respectively. The scanning electron microscope (SEM) observations showed that the BF/CF hybrid fibers reinforced composites had better interfacial adhesion.     

玄武岩生料乳浊釉的研究

分析了玄武岩的矿物组成、化学组成及烧成性能,对长石、滑石、硼砂对玄武岩釉料的影响进行了实验,确定适于卫生陶瓷生料釉的配方。     

高应力硬脆玄武岩微裂隙分布及破裂发展辨识

白鹤滩水电站区域构造地应力高,玄武岩坚硬性脆、隐微裂隙发育,地下厂房开挖过程顶拱浅层应力型开裂和深层破裂特征明显,传统的声波、钻孔电视测试和变形监测等方法难以精确获取岩体微破裂裂隙分布特征及高应力破裂发展特征信息。采用高精度超声波成像综合测试系统新方法,对厂房顶拱应力破裂破坏显著区域进行了多次重复测试。测试成果揭示：① 厂房顶拱上方岩体赋存的裂隙面倾角以陡倾角为主,优势倾角范围为45.98°~52.06°;裂隙面的倾向为NWW向,优势倾向范围为276.36°~292.01°,裂隙面倾角和倾向随深度变化不明显。② 顶拱浅层围岩破裂裂纹集中区一般在3.50~4.25 m的深度范围内,围岩深部诱发破裂裂纹区主要分布在9.68~10.11,16.12~16.32,21.45~21.77 m范围。③ 局部岩体受顶拱应力场不断调整演化作用,出现岩体破裂随时间加剧的现象。该成果高精度地辨识了玄武岩不同深度微破裂裂隙面分布特征、深度范围和应力破裂发展特点,对研究高应力硬脆玄武岩力学特性和响应机理提供了坚实基础资料,为工程开挖施工和动态支护设计发挥了重要支撑作用。